| 638 | 5 | 68 |
| 下载次数 | 被引频次 | 阅读次数 |
近年来,纤维素离子凝胶由于其性质和应用的可变性已被广泛研究,将离子液体捕获在可生物降解的固体基质中而不失去其特性的能力使这种材料成为化石燃料衍生材料的替代品。离子液体作为具有高热稳定性和化学稳定性的非挥发性溶剂,可以为纤维素加工提供更环保的可调平台。通过基于离子液体和纤维素材料的研究,获得了更高强度、更高电导率及更富泛用性的凝胶。综述了以各种纤维素及其衍生物作为基底制备的纤维素离子凝胶在柔性传感器、聚合物电解质和医学等方面的应用,以期对该类材料的进一步研究起到促进作用。
Abstract:In recent years, cellulose ionogel has been widely studied because of its variability in properties and applications. The ability to trap ionic liquids in biodegradable solid matrices without losing their properties makes this material a substitute for fossil fuel derived materials. Ionic liquids, as non-volatile solvents with high thermal and chemical stabilities, can provide a more environmentally friendly and adjustable platform for cellulose processing. Through the research based on ionic liquids and cellulose materials, the gels with higher strength, higher conductivity and greater versatility are obtained. The applications of cellulose ionogel prepared with various cellulose and their derivatives as the substrates in flexible sensors, polymer electrolytes and medicine are reviewed in order to promoting the further research of this kind of materials.
[1] MA K L,JIN X Y,ZHENG M X,et al.Dissolution and functionalization of celluloses using 1,2,3-triazolium ionic liquid [J].Carbohydrate Polymer Technologies and Applications,2021,2:100109.
[2] FAN Z S,CHEN J B,SUN S Q,et al.A novel strategy to reduce the viscosity of cellulose-ionic liquid solution assisted by transition metal ions [J].Carbohydrate Polymers,2021,256:117535.
[3] LI Y,WANG J J,LIU X M,et al.Towards a molecular understanding of cellulose dissolution in ionic liquids:anion/cation effect,synergistic mechanism and physicochemical aspects [J].Chemical Science,2018,9(17):4027-4043.
[4] DANDEGAONKAR G,AHMED A,SUN L Y,et al.Cellulose based flexible and wearable sensors for health monitoring [J].Materials Advances,2022,3(9):3766-3783.
[5] HARON G A S,MAHMOOD H,NOH M H B,et al.Ionic liquid assisted nanocellulose production from microcrystalline cellulose:correlation between cellulose solubility and nanocellulose yield via COSMO-RS prediction [J].Journal of Molecular Liquids,2022,368:120591.
[6] da SILVA J B A,VIEIRA S R,PESS?A L C,et al.Impact of ionic liquid’s cation alkyl chain length and reaction time on cellulose nanocrystals preparation [J].Carbohydrate Polymer Technologies and Applications,2023,6:100390.
[7] HABIBI Y,LUCIA L A,ROJAS O J.Cellulose nanocrystals:chemistry,self-assembly,and applications [J].Che-mical Reviews,2010,110(6):3479-3500.
[8] ZHANG C H,CUI J S,SUI W B,et al.High heat resis-tance,strength,and toughness of epoxy resin with cellulose nanofibers and structurally designed ionic liquid [J].Chemical Engineering Journal,2023,478:147063.
[9] QU B,XIAO Z L,LUO Y G,et al.Carboxymethyl cellulose capped zinc oxide nanoparticles dispersed in ionic liquid and its antimicrobial effects against foodborne pathogens [J].Carbohydrate Polymer Technologies and Applications,2023,6:100364.
[10] GAO X L,LIU H,SHUAI J B,et al.Rapid transesterification of cellulose in a novel DBU-derived ionic liquid:efficient synthesis of highly substituted cellulose acetate [J].International Journal of Biological Macromolecules,2023,242:125133.
[11] SADIGHIAN H,AHMADI E,MOHAMADNIA Z.Application of imidazolium based ionic liquids grafted on microcrystalline cellulose as demulsifiers for water in crude oil (W/O) emulsions [J].Carbohydrate Polymers,2023,302:120406.
[12] HOVORKA ?,HRDLIKA Z,JENI?TOVá A,et al.Impacts of ions on the plasticization of cellulose triacetate by fluorinated ionic liquids:thermal properties,microscopy,Raman spectra,and sorption of pure enantiomers [J].Polymer,2024,290:126502.
[13] LI F H,SHEN Y Y,DENG Y P,et al.Experimental and theoretical studies on dissolution and regeneration of microcrystalline cellulose with dihydroxyl ionic liquids [J].Journal of Molecular Liquids,2023,389:122928.
[14] ZHOU Y,ZHANG X C,YIN D X,et al.The solution state and dissolution process of cellulose in ionic-liquid-based solvents with different hydrogen-bonding basicity and microstructures [J].Green Chemistry,2022,24(9):3824-3833.
[15] KRUGLY E,PAULIUKAITYTE I,CIUZAS D,et al.Cellulose electrospinning from ionic liquids:the effects of ionic liquid removal on the fiber morphology [J].Carbohydrate Polymers,2022,285:119260.
[16] PROTZ R,LEHMANN A,GANSTER J,et al.Solubility and spinnability of cellulose-lignin blends in aqueous NMMO [J].Carbohydrate Polymers,2021,251:117027.
[17] HUANG J C,ZHONG Y,ZHANG L N,et al.Extremely strong and transparent chitin films:a high-efficiency,energy-saving,and “green” route using an aqueous KOH/urea solution [J].Advanced Functional Materials,2017,27(26):1701100.
[18] CAO M J,CHU J L,FAN X J,et al.Poly (ionic liquid) filled and cross-linked bacterial cellulose-based organic-inorganic composite anion exchange membrane with significantly improved ionic conductivity and mechanical strength [J].Journal of Membrane Science,2023,675:121558.
[19] 徐德增,李丹,徐磊.咪唑类离子液体溶解纤维素的研究进展 [J].合成纤维工业,2011,34(5):48-51.XU D Z,LI D,XU L.Research progress in cellulose dissolution in imidazolium ionic liquids [J].China Synthetic Fiber Industry,2011,34(5):48-51(in Chinese).
[20] 李茂刚,罗康碧,李沪萍,等.离子液体溶解纤维素的应用研究进展 [J].化工新型材料,2018,46(4):39-42.LI M G,LUO K B,LI H P,et al.Progress on the application of ionic liquid to dissolve cellulose [J].New Chemical Materials,2018,46(4):39-42(in Chinese).
[21] UEKI T,WATANABE M.Macromolecules in ionic liquids:progress,challenges,and opportunities [J].Macromolecules,2008,41(11):3739-3749.
[22] GAYET F,VIAU L,LEROUX F,et al.Unique combination of mechanical strength,thermal stability,and high ion conduction in PMMA-silica nanocomposites containing high loadings of ionic liquid [J].Chemistry of Materials,2009,21(23):5575-5577.
[23] 蒋晶,苏光耀.离子液体聚合物电解质的研究进展 [J].电池,2005,35(6):474-476.JIANG J,SU G Y.Research progress in ionic liquid-polymer electrolytes [J].Battery Bimonthly,2005,35(6):474-476(in Chinese).
[24] le BIDEAU J,VIAU L,VIOUX A.Ionogels,ionic liquid based hybrid materials [J].Chemical Society Reviews,2011,40(2):907-925.
[25] SMITH C J,WAGLE D V,O’NEILL H M,et al.Bacterial cellulose ionogels as chemosensory supports [J].ACS Applied Materials & Interfaces,2017,9(43):38042-38051.
[26] SMITH C J,GEHRKE S,HOLLóCZKI O,et al.NMR relaxometric probing of ionic liquid dynamics and diffusion under mesoscopic confinement within bacterial cellulose ionogels [J].The Journal of Chemical Physics,2018,148(19):193845.
[27] LIU K K,LV J C,FAN G D,et al.Flexible and robust bacterial cellulose-based ionogels with high thermoelectric properties for low-grade heat harvesting [J].Advanced Functional Materials,2022,32(6):2107105.
[28] JIANG G Y,WANG G,ZHU Y,et al.A scalable bac-terial cellulose ionogel for multisensory electronic skin [J].Research,2022,2022:9814767.
[29] FAN G D,LIU K K,SU H,et al.Mesoscopic confined ionic thermoelectric materials with excellent ionic conductivity for waste heat harvesting [J].Chemical Engineering Journal,2022,434:134702.
[30] BU X F,ZHOU B G,LI J C,et al.Orange peel-like triboelectric nanogenerators with multiscale micro-nano structure for energy harvesting and touch sensing applications [J].Nano Energy,2024,122:109280.
[31] NEVSTRUEVA D,MURASHKO K,VUNDER V,et al.Natural cellulose ionogels for soft artificial muscles [J].Colloids and Surfaces:B,2018,161:244-251.
[32] VILLAR-CHAVERO M M,DOMíNGUEZ J C,ALONSO M V,et al.Chitosan-reinforced cellulosic bionogels:viscoelastic and antibacterial properties [J].Carbohydrate Polymers,2020,229:115569.
[33] VILLAR-CHAVERO M M,DOMíNGUEZ J C,ALONSO M V,et al.Viscoelastic properties of physical cellulosic bionogels of cholinium lysinate [J].International Journal of Biological Macromolecules,2019,133:262-269.
[34] GUO L Z,ZHANG L,WANG Z M,et al.Direct construction of strong,tough,conductive,and adhesive hydrogel bioelectronics enabled by salt-dissolved cellulose [J].Materials Today Communications,2023,37:107002.
[35] LI M F,XU H M,LUO M Y,et al.Wearable ionogel fiber-based ionic thermoelectric device for low-grade human body heat harvesting [J].Chemical Engineering Journal,2024,485:149784.
[36] GUO S F,ZHAO K,FENG Z Q,et al.High performance liquid crystalline bionanocomposite ionogels prepared by in situ crosslinking of cellulose/halloysite nanotubes/ionic liquid dispersions and its application in supercapacitors [J].Applied Surface Science,2018,455:599-607.
[37] FU X L,CHEN Y X,WANG W,et al.Self-adhesive and anti-fatigue cellulose-polyacrylate ionogels prepared by ultraviolet curing used as biopotential electrodes [J].International Journal of Biological Macromolecules,2022,218:533-542.
[38] WU D,WANG M,YU W,et al.A robust,biodegradable and recyclable all-cellulose ionogel from low-value wood [J].Chemical Engineering Journal,2024,486:150121.
[39] ZHOU Y,WANG L L,LIU Y P,et al.Transparent,stretchable,self-healing,and self-adhesive ionogels for fle-xible multifunctional sensors and encryption systems [J].Chemical Engineering Journal,2024,484:149632.
[40] ZHU M N,GONG D,JI Z X,et al.Cellulose-reinforced poly(ionic liquids) composite hydrogel for infected wounds therapy and real-time reliable bioelectronic [J].Chemical Engineering Journal,2023,476:146816.
[41] SHAN C C,CHE M D,CHOLEWINSKI A,et al.Multifunctional nanocrystalline cellulose ionogels toward tough and sustainable materials [J].Cell Reports Physical Science,2023,4(8):101511.
[42] WANG Z H,LIU J H,ZHANG J X,et al.Novel chemically cross-linked chitosan-cellulose based ionogel with self-healability,high ionic conductivity,and high thermo-mechanical stability [J].Cellulose,2020,27(9):5121-5133.
[43] VILLAR-CHAVERO M M,DOMíNGUEZ J C,ALONSO M V,et al.Tuning the rheological properties of cellulosic ionogels reinforced with chitosan:the role of the deacetylation degree [J].Carbohydrate Polymers,2019,207:775-781.
[44] CHOI W,ABRAHAM A,KO J,et al.Anisotropic alignment of bacterial nanocellulose ionogels for unconventionally high combination of stiffness and damping [J].ACS Applied Materials & Interfaces,2022,14(26):30056-30066.
[45] THIEMANN S,SACHNOV S J,PETTERSSON F,et al.Cellulose-based ionogels for paper electronics [J].Advanced Functional Materials,2014,24(5):625-634.
[46] CHEN Q F,CHENG B B,WANG Z Q,et al.Rarely negative-thermovoltage cellulose ionogel with simultaneously boosted mechanical strength and ionic conductivity via ion-molecular engineering [J].Journal of Materials Chemistry:A,2023,11(5):2145-2154.
[47] ZHU A T,HUANG J,XIE H B,et al.Use of a superbase/DMSO/CO2 solvent in order to incorporate cellulose into organic ionogel electrolyte for flexible supercapacitors [J].Chemical Engineering Journal,2022,446:137032.
[48] SIMOTWO S K,CHINNAM P R,WUNDER S L,et al.Highly durable,self-standing solid-state supercapacitor based on an ionic liquid-rich ionogel and porous carbon nanofiber electrodes [J].ACS Applied Materials & Interfaces,2017,9(39):33749-33757.
[49] DANG C,SHAO C Y,LIU H C,et al.Cellulose melt processing assisted by small biomass molecule to fabricate recyclable ionogels for versatile stretchable triboelectric nanogenerators [J].Nano Energy,2021,90:106619.
[50] LEE H,ERWIN A,BUXTON M L,et al.Shape persistent,highly conductive ionogels from ionic liquids reinforced with cellulose nanocrystal network [J].Advanced Functional Materials,2021,31(38):2103083.
[51] MIGLIORINI L,PIAZZONI C,POHAKO-ESKO K,et al.All-printed green micro-supercapacitors based on a natural-derived ionic liquid for flexible transient electronics [J].Advanced Functional Materials,2021,31(27):2102180.
[52] GONZáLEZ-GIL R M,BORRàS M,CHBANI A,et al.Sustainable and printable nanocellulose-based ionogels as gel polymer electrolytes for supercapacitors [J].Nanomate-rials,2022,12(2):273.
[53] SONG H Z,LUO Z Q,ZHAO H C,et al.High tensile strength and high ionic conductivity bionanocomposite ionogels prepared by gelation of cellulose/ionic liquid solutions with nano-silica [J].RSC Advances,2013,3(29):11665-11675.
[54] KOWALCZUK J,BIELEJEWSKI M,TRITT-GOC J.Ionic liquid dynamics and electrical conductivity under confinement within micro and nanocellulose ionogels [J].Cellulose,2023,30(6):3551-3567.
[55] ALEKSEEVA O,SHIBAEVA V,NOSKOV A,et al.Ionic liquid/Na-bentonite/microcrystalline cellulose ionogels as conductive multifunctional materials [J].Coatings,2023,13(8):1475.
[56] LI P J,ZHANG Y G,FA W J,et al.Synthesis of a grafted cellulose gel electrolyte in an ionic liquid ([Bmim] I) for dye-sensitized solar cells [J].Carbohydrate Polymers,2011,86(3):1216-1220.
[57] RANA H H,PARK J H,GUND G S,et al.Highly conducting,extremely durable,phosphorylated cellulose-based ionogels for renewable flexible supercapacitors [J].Energy Storage Materials,2020,25:70-75.
[58] KADOKAWA J I,MURAKAMI M A,KANEKO Y.A facile preparation of gel materials from a solution of cellulose in ionic liquid [J].Carbohydrate Research,2008,343(4):769-772.
[59] KADOKAWA J I,MURAKAMI M A,TAKEGAWA A,et al.Preparation of cellulose-starch composite gel and fibrous material from a mixture of the polysaccharides in ionic liquid [J].Carbohydrate Polymers,2009,75(1):180-183.
[60] HAQ M A,HABU Y,YAMAMOTO K,et al.Ionic liquid induces flexibility and thermoplasticity in cellulose film [J].Carbohydrate Polymers,2019,223:115058.
[61] RIZZO C,MISIA G,MARULLO S,et al.Bio-based chitosan and cellulose ionic liquid gels:polymeric soft materials for the desulfurization of fuel [J].Green Chemistry,2022,24(3):1318-1334.
[62] HOPSON C,RIGUAL V,DOMíNGUEZ J C,et al.A new approach for the use of cellulose-rich solids from biorefinery in the formulation of gel-like materials [J].Indus-trial Crops and Products,2022,186:115230.
[63] KIKUCHI K,KANEKO K,FUKAYA R,et al.Influence of hydrostatic pressure during gelation on physicochemical properties of cellulose hydrogels prepared from ionic liquid/DMSO solution [J].Journal of Molecular Liquids,2023,381:121810.
[64] KIKUCHI K,KANEKO K,SEONJU J,et al.Influence of gelation temperature on physicochemical properties of cellulose hydrogels prepared from ionic liquid/DMSO solution [J].Journal of Molecular Liquids,2023,376:121465.
[65] SINGH A,SINGH J,SINGH N,et al.Development and characterization of gelatin/carboxymethyl cellulose based polymeric film with inclusion of ionic liquid to enhance the shelf life of food [J].Food Packaging and Shelf Life,2024,42:101251.
[66] de OLIVEIRA SANTOS S S,MILLáN R D S,SPEZIALI M G.Versatile grafted microcrystalline cellulose with ionic liquid as new Losartan-controlled release material [J].European Polymer Journal,2020,124:109490.
[67] HOPSON C,VILLAR-CHAVERO M M,DOMíNGUEZ J C,et al.Cellulose ionogels,a perspective of the last decade:a review [J].Carbohydrate Polymers,2021,274:118663.
[68] DU Y C,FENG G F.When nanocellulose meets hydrogels:the exciting story of nanocellulose hydrogels taking flight [J].Green Chemistry,2023,25(21):8349-8384.
基本信息:
DOI:10.13250/j.cnki.wndz.25020104
中图分类号:TQ427.26
引用信息:
[1]潘海树,梁霞,陆安松,等.纤维素离子凝胶的研究进展及应用[J].微纳电子技术,2025,62(02):44-60.DOI:10.13250/j.cnki.wndz.25020104.
基金信息:
广西民族大学科研基金资助项目(引进人才科研启动项目2022KJQD13);广西民族大学自治区级大学生创新创业训练计划项目(S202410608031,S202410608034);广西民族大学研究生教育创新计划项目(gxun-chxs2024109); 广西科技计划项目(广西科技基地和人才专项桂科AD23026052); 广西高校中青年教师科研基础能力提升项目(2023KY0179); 广西生物活性分子研究与评价重点实验室开放课题(BMRE2024-KF05)
2024-07-22
2024
2024-09-29
2024
1
2025-02-15
2025-02-15