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聚乳酸(PLA)因具有生物可降解、生物相容性好等而广泛应用于生物医疗、食品包装、面料等领域。基于PLA材料的增材制造技术日益受到广泛关注,成为增材制造产业发展中重要的研究方向。综述了PLA材料的材料挤出、激光烧结成型和光聚合三种打印工艺的优缺点,介绍了对PLA材料存在的缺陷进行物理、化学改性的研究进展。以纤维、纳米陶瓷和金属颗粒复合材料为例,阐明了PLA材料改性后的功能。重点介绍了PLA打印产品在生物医疗、环保、新能源、家居、智能食品包装、可穿戴等领域的应用。此外还概述了一些PLA材料在4D打印领域的研究进展。同时阐明了现阶段基于PLA增材制造的亟需解决问题,为PLA增材创造的研究和应用提供了参考。
Abstract:Polylactic acid(PLA) is widely used in fields such as biomedicine, food packaging and fabrics due to its biodegradability and good biocompatibility. The additive manufacturing technology based on PLA materials is increasingly receiving widespread attention and has become an important research field in the development of the additive manufacturing industry. The advantages and disadvantages of three printing processes for PLA materials of material extrusion, laser sintering and photopolymerization are reviewed. The research progress of physical and chemical modification of the defects in PLA materials are introduced. The functions of PLA materials after modification are elucidated using fiber, nano-ceramic and metal particle composites as examples. The applications of PLA printing products in biomedical, environmental protection, new energy, home, smart food packaging, wearable and other fields was highlighted. In addition, the research progress of PLA materials in the field of 4D printing is briefly reviewed. Meanwhile, the urgent problems for PLA additive manufacturing are elucidated, providing references for the research and application of PLA additive manufacturing.
[1] Wohlers Associates.3D printing and additive manufacturing state of the industry [R].2023:10-50.
[2] 周伟民,闵国全.纳米增材制造[J].微纳电子技术,2018,55(3):206-218.ZHOU W M,MIN G Q.Additive nanomanufacturing[J].Micronanoelectronic Technology,2018,55(3):206-218.
[3] 蔡云冰,刘志鹏,张子龙,等.聚乳酸材料在 3D 打印中的 研究 与应 用进 展 [J].应用 化工,2019,48(6):1463-1468.CAI Y B,LIU Z P,ZHANG Z L,et al.Research and application of polylactic acid in 3D printing[J].Applied Chemical Industry,2019,48(6):1463-1468.
[4] 樊聪,杨东辉,苏经纬,等.3D 打印用聚乳酸材料研究[J].科技创新与应用,2023,33:80-85.FAN C,YANG D H,SU J W,et al.Research on PLA of 3D printing[J].Technology Innovation and Application,2023,33:80-85.
[5] FARAHANI A,ZAREI-HANZAKI A,ABEDI H R,et al.Polylactic acid piezo-biopolymers:chemistry,structural evolution,fabrication methods,and tissue engineering applications[J].Journal of Functional Biomaterials,2021,12(4):71.
[6] CRUMP S S.Apparatus and method for creating three-dimensional objects:USPatent5121329[P].1992-06-09.
[7] CESARANO J,SEGALMAN R,CALVERT P.Robocasting provides moldless fabrication fiom slurry deposition[J].Materials Science,1998,148(4):94-96.
[8] DECKARD C R,MCCLURE P F.Selective laser sintering[D].Austin:University of Texas at Austin,1988.
[9] SKOOG S A,GOERING P L,NARAYAN R J.Stereolithography in tissue engineering[J].Journal of Materials Science:Materials in Medicine,2014,25:845-856.
[10] 王伊卿,贾志洋,赵万华,等.面曝光快速成形关键技术及研究现状[J].机械设计与研究,2009,25(2):96-100.WANG Y Q,JIA Z Y,ZHAO W H,et al.The key technology and research status of mask projection stereolithography[J].Machine Design and Research,2009,25(2):96-100.
[11] 邹静娴,吴荣治.数字微镜器件(DMD)[J].液晶与显示,2003,18(6):445-449.ZOU J X,WU R Z.Digital micromirror device[J].Chinese Journal of Liquid Crystals and Displays,2003,18(6):445-449.
[12] BHAGIAA S,BORNANI K,AGRAWAL R C,et al.Cri-tical review of FDM 3D printing of PLA biocomposites filled with biomass resources,characterization,biodegradability,upcycling and opportunities for biorefineries[J].Applied Materials Today,2021,24:1-19.
[13] CORAPI D,MORETTINI G,PASCOLETTI G,et al.Characterization of a polylactic acid (PLA) produced by fused deposition modeling (FDM) technology[J].Procedia Structural Integrity,2019,24:289-295.
[14] FICZERE P,BORBAS L,FALK G,et al.Experimental determination of material model of machine parts produced by selective laser sintering (SLS) technology[J].Mate-rials Today:Proceedings,2018,5(13):26489-26494.
[15] 潘腾,朱伟,闫春泽,等,激光选区烧结 3D 打印成形生物高分子材料研究进展[J].高分子材料科学与工程,2016,32(3):178-183.PAN T,ZHU W,YAN C Z,et al.Selective laser sintering 3D printing of biomedical polymer materials[J].Polymer Materials Science and Engineering,2016,32(3):178-183.
[16] WU L B,SHRESTHA P,IAPICHINO M,et al.Characterization method for calculating diffusion coefficient of drug from polylactic acid (PLA) microneedles into the skin[J].Journal of Drug Delivery Science and Technology,2021,61:1-11.
[17] MELCHELS F P W,VELDERS A H,FEIJEN J,et al,Photo-cross-linked poly(dl-lactide)-based networks.structural characterization by HR-MAS NMR spectroscopy and hydrolytic degradation behavior [J].Macromolecules,2010,43(20):8570-8579.
[18] SAKUNPHOKESUP K,AUMNATE C,POTIYARAJ P.Bio-based resin/cellulose composites for UV-assisted 3D printed orthopedic casts[J].Journal of Physics:Confe-rence Series,2022,2175:1-7.
[19] SAED A B,BEHRAVESH A H,HASANNI S.An in vitro study on the key features of poly L-lactic acid/biphasic calcium phosphate scaffolds fabricated via DLP 3D printing for bone grafting[J].European Polymer Journal,2020,41(12):110057-1-110057-10.
[20] 王正祥.我国聚乳酸产业发展现状与对策研究[J].中国工程科学,2021,23(6):155-166.WANG Z X.China's polylactic acid industry:current status and development strategies[J].Strategic Study of CAE,2021,23(6):155-166.
[21] 崔永辉,虞立果,贾明印.连续纤维增强 PLA 复合材料3D 打印制备技术研究[J].纤维复合材料,2020(4):95-100.CUI Y H,YU L G,JIA M Y.Study on 3D printing technology of continuous fiber reinforced PLA composite[J].Fiber Composites,2020(4):95-100.
[22] 夏法锋,张红哲,李洋.基于 3D 打印技术制备 CF-PLA 纤维及性能研究[J].塑料工业,2023,51(8):152-157.XIA F F,ZHANG H Z,LI Y.Preparation and perfor-mance study of CF-PLA fibers based on 3D printing[J].China Plastics Industry,2023,51(8):152-157.
[23] PAZ-GONZALEZ J A,VELASCO-SANTOS C,VILLARREAL-GOMEZ L J,et al.Structural composite based on 3D printing polylactic acid/carbon fiber laminates (PLA/CFRC) as an alternative material for femoral stem prosthesis[J].Journal of the Mechanical Behavior of Biomedical Materials,2023,138:105632.
[24] ZOU L H,ZUO H M,DOU T T,et al.3D printing of carbon fiber powder/polylactic acid with enhanced electromagnetic interference shielding[J].Diamond and Related Materials,2024,141(1):110583.
[25] 李飞,PLA/SiC复合材料制备及其3D打印成型工艺研究[D].北京:北京化工大学,2019.LI F.Research on the preparation of PLA/SiC composites and 3D printing molding process[D].Beijing:Beijing University of Chemical Technology,2019.
[26] ZUO Y F,CHEN K,LI P,et al.Effect of nano-SiO2 on the compatibility interface and properties of polylactic acid-grafted-bamboo fiber/polylactic acid composite[J].International Journal of Biological Macromolecules,2020,157(8):177-186.
[27] SONG T,LIU M,TIAN J E,et al.Effect of PLA/TiO2/Lg filler competition and synergy on crystallization beha-vior,mechanics and functionality of composite foaming materials[J].Polymer,2023,271(4):125797.
[28] PREMPHET P,LEKSAKUL K,BOONYAWAN D.Process parameters optimization and mechanical properties of 3D PLA/HA printing scaffold[J].Materials Today:Proceedings,2023:10.1016/j.matpr.2023.04.124(in press).
[29] WANG W Z,ZHANG B Q,LI M X.3D printing of PLA/n-HA composite scaffolds with customized mechanical properties and biological functions for bone tissue enginee-ring[J].Composites Part B:Engineering,2021,224:109192.
[30] TEDLA G,ROGERS K.Characterization of 3D printing filaments containing metal additives and their particulate emissions[J].Science of the Total Environment,2023,875(1):162648.
[31] ZHANG Q,WEBER R J,LUXTON T P,et al.Metal compositions of particle emissions from material extrusion 3D printing:emission sources and indoor exposure modeling[J].Science of the Total Environment,2023,860:160512.
[32] 王萍,王先丽,吴迪.生物降解Mg增强PLA复合膜用于引导骨再生的抗茵性能研究[J].南京医科大学学报(自然科学版),2022,42(7):965-972.WANG P,WANG X L,WU D,et al.Research on antibacterial properties of the biodegradable magnesium reinforced polylactic acid composite membrane for guided bone regene-ration[J].Journal of Nanjing Medicial University(Natural Sciences),2022,42(7):965-972.
[33] 李春旭.3D打印PLGA/β-TCP/Zn支架通过持续释放Zn2+提髙成骨诱导和抗炎能力促进骨缺损修复[D].北京:北京协和医学院,2022.LI C X.Continuously released Zn2+in 3D-printed PLGA/β-TCP/Zn scaffolds for bone defects repair by improving the osteoinductivity and anti-innammatory ability[D].Beijing:Peking Union of Medical College,2022.
[34] PASCUAL-GONZáLEZ C,de la VEGA J,THOMPSON C,et al.Processing and mechanical properties of novel biodegradable poly-lactic acid/Zn 3D printed scaffolds for application in tissue regeneration[J].Journal of the Mechanical Behavior of Biomedical Materials,2022,132:105290.
[35] YAN T M,YE X C,HE E Y,et al.GR-Fe3O4/PLA 3D printing composite materials with excellent microwave absorption properties[J].Journal of Alloys and Compounds,2024,972:172799.
[36] SANDANAMSAMY L,MOGAN J,RAJAN K,et al.Effect of process parameter on tensile properties of FDM printed PLA[J].Materials Today:Processings,2023.
[37] KIM M E,JEONG J H,LEE J Y,et al.Electrically conducting and mechanically strong graphene-polylactic acid composite for 3D printing[J].ACS Appl Mater Interfaces,2019,11(12):11841-11848.
[38] LIN C,LIU L W,LIU Y J,et al.4D printing of shape memory polybutylene succinate/polylactic acid (PBS/PLA) and its potential applications[J].Composite Structures,2022,279(1):114729.
[39] PETOUSIS M,NINIKAS K,VIDAKIS N,et al.Multifunctional PLA/CNTs nanocomposites hybrid 3D printing integrating material extrusion and CO2 laser cutting[J].Journal of Manufacturing Processes,2023,86:237-252.
[40] GUO W,YANG Y J,LIU C,et al.3D printed TPMS structural PLA/GO scaffold:Process parameter optimization,porous structure,mechanical and biological properties[J].Journal of the Mechanical Behavior of Biomedical Materials,2023,142:105848.
[41] TYLER B,GULLOTTI D,MANGRAVITI A,et al,Polylactic acid (PLA) controlled delivery carriers for biomedical applications[J].Advanced Drug Delivery Reviews,2016,107:163-175.
[42] PENTEK A,NYITRAI M,SCHIER A,et al.The effect of printing parameters on electrical conductivity and mechanical properties of PLA and ABS based carbon compo-sites in additive manufacturing of upper limb prosthetics[J].Crystals,2020,10:398-1-398-12.
[43] 林坷升,刘洁,刘方政,等.油墨直写打印纳米羟基磷灰石/聚乳酸复合材料:制备及性能研究[J].机械 工程 学报,2020,56(9):234-242.LIN K S,LIU J,LIU F Z,et al.Preparation and properties of ink direct writing nano-hydroxyapatite/polylactic acid composite materials[J].Journal of Mechanical Enginee-ring,2020,56(9):234-242.
[44] WU L B,SHRESTHA P,IAPICHINO M,et al.Characterization method for calculating diffusion coefficient of drug from polylactic acid (PLA) microneedles into the skin[J].Journal of Drug Delivery Science and Technology,2021,61:102192.
[45] 滕桂香,杨怡凡,侯苏童,等.一步法制备 PLA/PDA/Ag 多孔抗菌纳米纤维膜及其促进伤口愈合作用研究[J].材料导报,2023,37(18):240-245.TENG G X,YANG Y F,HOU S T,et al.Preparation of PLA/PDA/Ag porous antibacterial nanofibrous membrane by one-step and their effect on promoting wound healing[J].Materials Reports,2023,37(18):240-245.
[46] HE J L,YUE T L,MCCUTCHEON J R,et al.Recent developments in 3D-printed membranes for water desalination[J].Journal of Physics:Energy,2024,6:012002.
[47] ZHOU G,WANG K P,LIU H W,et al.Three-dimensio-nal polylactic acid@graphene oxide/chitosan sponge bionic filter:highly efficient adsorption of crystal violet dye[J].International Journal of Biological Macromolecules:Structure,Function and Interactions,2018,113:792-803.
[48] LEHNEN A C,HANKE S,SCHNEIDE M.Modification of 3D-printed PLA structures using photo-iniferter polyme-rization:toward on-demand antimicrobial water filters[J].Macromol Rapid Commun,2023,44(22):2300408.
[49] FIJO? N,AGUILAR-SANCHEZ A,RUIZ-CALDAS M X,et al.3D printed polylactic acid (PLA) filters reinforced with polysaccharide nanofibers for metal ions capture and microplastics separation from water[J].Chemical Engineering Journal,2023(457):141153.
[50] 郜阳,张桐赫,高腾飞,等.3D打印聚乳酸膜及其油-水分离性能[J/OL].石油学报(石油加工),2024,40(2):546-553.GAO Y,ZHANG T H,GAO T F,et al.3D printing of polylactic acid membranes for oil-water separation and its performance[J/OL].Acta Petrolei Sinica(Petroleum Processing Section),2024,40(2) :546-553.
[51] MAUREL A,HAUKKA M,MACDONALD E,et al.Considering lithium-ion battery 3D-printing via thermoplastic material extrusion and polymer powder bed fusion[J].Additive Manufacturing,2021,37:101651.
[52] MENSING J P,LOMAS T,TUANTRANONT A.2D and 3D printing for graphene based supercapacitors and batte-ries:a review[J].Sustainable Materials and Technologies,2020,25:e00190.
[53] 陈雪.太阳能聚焦 3D 打印系统设计及 PLA 熔丝打印工艺研究[D].上海:东华大学,2023.CHEN X.Design of solar focused 3D printing system and research on PLA fused printing technology[D].Shanghai:Donghua University,2023.
[54] MAUREL A,COURTY M,FLEUTOT B,et al.Highly loaded graphite-polylactic acid composite-based filaments for lithium-ion battery three-dimensional printing[J].Che-mistry Materials,2018,30(21):7484-7493.
[55] FOSTER C W,DOWN M P,ZHANG Y,et al.3D printed graphene based energy storage devices[J].Scientific Reports,2017,7:42233.
[56] MAUREL A,GRUGEON S,FLEUTOT B,et al.Three-dimensional printing of a LiFePO4/graphite battery cell via fused deposition modeling[J].Scientific Reports,2019,9(1):18031.
[57] WAN J Y,XIE J,KONG X,et al.Ultrathin,flexible,solid polymer composite electrolyte enabled with aligned nanoporous host for lithium batteries[J].Nature Nanotechnology,2019,14(7):705-711.
[58] FOSTER C W,DOWN M P,ZHANG Y,et al.3D printed graphene based energy storage devices[J].Scientific Reports,2017,7:42233.
[59] GUPTA V,ALAM F,VERMA P,et al.Additive manufacturing enabled,microarchitected,hierarchically porous polylactic-acid/lithium iron phosphate/carbon nanotube nanocomposite electrodes for high performance Li-ion batteries[J].Journal of Power Sources,2021,494(5):229625.
[60] XUN Y R,ZHANG K X,JONHSON W.A minireview on 3D printing for electrochemical water splitting electrodes and cells[J].APL Material,2023,11(6):1-24.
[61] MOJABI S,AFSAHI N,NASERI N.Additive manufacturing:new paradigm for developing water splitting systems[J].International Journal of Hydrogen Energy,2024,49:116-142.
[62] BROWNE M P,URBANOVA V,PLUTNAR J,et al.Inherent impurities in 3D-printed electrodes are responsible for catalysis towards water splitting[J].Journal of Materials Chemistry,2020,8:1120-1126.
[63] HUGHES J P,SANTOS P L,DOWN M P,et al.Single step additive manufacturing (3D printing) of electrocatalytic anodes and cathodes for efficient water splitting[J].Sustainable Energy Fuels,2019,4(1):302-311.
[64] 王琛,丁可青,周徵艺.3D打印聚乳酸灯饰产品的设计应用[J].工程塑料应用,2022,50(10):72-76.WANG C,DING K Q,ZHOU Z Y.Design and application of 3D printing polylactic acid lighting products[J].Engineering Plastics Application,2022,50(10):72-76.
[65] 张紫阳,孟家光,薛涛,等.3D打印参数对柔性聚乳酸服装面料力学性能的影响[J].合成纤维,2021,50(4):31-34.ZHANG Z Y,MENG J G,XUE T,et al.Effects of 3D printing parameters on mechanical property of flexible polylactic acid fabrics[J].Synthetic Fiber in China,2021,50(4):31-34.
[66] 杨露,薛涛,孟家光,等.3D 打印柔性服装面料的负离子功能整理及其性能[J].纺织学报,2021,42(8):102-108.YANG L,XUE T,MENG J G,et al.Anion functional finish and properties of 3D printed flexible garment fabrics[J].Journal of Textile Research,2021,42(8):102-108.
[67] SHOEB M,LKUMAR L,HALEEM A.3D printed medical surgical cotton fabric-poly lactic acid biocomposite:a feasibility study[J].Sustainable Operations and Computers,2023,4:130-146.
[68] JAYSWAL A,LIU J,HARRIS G,et al.Thermo-mecha-nical properties of composite filaments for 3D printing of fabrics[J].Journal of Thermoplastic Composite Mate-rials,2023,36(12):4800-4825.
[69] TRACEY C T,PREDEINA A L,KRIVOSHAPKINA E F.A 3D printing approach to intelligent food packaging[J].Trends in Food Science & Technology,2022,127:87-98.
[70] MURO-FRAGUAS I,SAINZ-GARCíA A,GóMEZ P F,et al.Atmospheric pressure cold plasma anti-biofilm coa-tings for 3D printed food tools[J].Innovative Food Science & Emerging Technologies,2020,64:102404.
[71] 芮正佳.3D打印用PLA的改性及在包装领域应用研究进展[J].塑料科技,2021,49(4):111-114.RUI Z J.Research progress of PLA modification for 3D printing and its application in packaging field[J].Plastics Science and Technology,2021,49(4):111-114.
[72] CHAIYA N,DARANARONG D,WORAJITTIPHON P.3D-printed PLA/PEO blend as biodegradable substrate coa-ting with CoCl2 for colorimetric humidity detection[J].Food Packaging and Shelf Life,2022,32:100829.
[73] PALANIYAPPAN S,SIVAKUMAR N K,BODAGHI M,et al.Preparation and performance evaluation of 3D printed poly lactic acid composites reinforced with silane functiona-lized walnut shell for food packaging applications [J].Food Packaging and Shelf Life,2024,41(1):101226.
[74] FERRETTI P,SANTI G M,LEON-CARDENAS C,et al.Production readiness assessment of low cost,multi-mate-rial,polymeric 3D printed moulds[J].Heliyon,2022,8:e11136.
[75] ROMERO P E,ARRIBAS-BARRIOS A,RODRIGUEZ-ALABANDA O,et al.Manufacture of polyurethane foam parts for automotive industry using FDM 3D printed molds[J].CIRP Journal of Manufacturing Science and Technology,2021,32:396-404.
[76] 董选普,左春林,凌宏江.V 法铸造模具的FDM 增材制造工艺研究[J].铸造工程,2021,45(1):30-36.DONG X P,ZUO C L,LING H J.Research on FDM process applied to vacuum process mold casting[J].Foundry Engineering,2021,45(1):30-36.
[77] 蔡新娟.汽车内饰用改性黄麻纤维毡/聚乳酸复合材料[D].上海:东华大学,2021.CAI X J.Modified jute fiber mat/polylactic acid composites for automobile interior decoration[D].Shanghai:Donghua University,2021.
[78] TáBI T,AGEYEVA T,KOVáCS J G.The influence of nucleating agents,plasticizers,and molding conditions on the properties of injection molded PLA products[J].Materials Today Communications,2022,32:103936.
[79] van der BORG G,WARNER H,IOANNIDIS M,et al.PLA 3D printing as a straightforward and versatile fabrication method for PDMS molds[J].Polymers,2023,15(6):1498.
[80] KALKAL A,KUMAR S,KUMAR P.Recent advances in 3D printing technologies for wearable (bio) sensors [J].Additive Manufacturing,2021,46:102088.
[81] CHO S J,NAM T S,CHOI S Y,et al.3D printed multi-channel EEG sensors for zebrafish[C]// Proceedings of the IEEE Sensors.Busan,Korea,2015.
[82] LEE J H,KIM H,HWANG J Y,et al.3D printed,customizable,and multifunctional smart electronic eyeglasses for wearable healthcare systems and human-machine interfaces[J].ACS Applied Materials & Interfaces,2020,12(19):21424-21432.
[83] PASCHOALIN R T,GOMES N O,ALMEIDA G F,et al.Wearable sensors made with solution-blow spinning poly(lactic acid) for non-enzymatic pesticide detection in agriculture and food safety[J].Biosensors and Bioelectronics,2022,199(3):113875.
[84] McDONAGH P,MCCOLE M,SKILLEN N,et al.3D printed carbon black-polylactic acid/copper (CB-PLA/Cu) sensor for improved sustainability in monitoring photocatalytic hydrogen peroxide evolution[J].Journal of Environmental Chemical Engineering,2023,11:111123.
[85] RANJAN N,SINGH R,AHUJA I P S.Development of PLA-HAp-CS-based biocompatible functional prototype:a case study[J].Journal of Thermoplastic Composite Materials,2020,33(3):305-323.
[86] CARKACI M E,SECMEN M.Design and prototype manufacturing of a feed system for Ku-band satellite communication by using 3D FDM/PLA printing and conductive paint technology[J].International Journal of RF and Microwave Computer-Aided Engineering,2020,30(4):1-8.
[87] HAMOUTI L,ELFARISSI O,OUTEMSSA O.Regression model for optimization and prediction of tensile strength of a PLA prototype printed[J].Journal of Advanced Computational Intelligence and Intelligent Informatics,2022,26(6):952-958.
[88] MEGDICH A,HABIBI M,LAPERRIERE L.A review on 4D printing:material structures,stimuli and additive manufacturing techniques[J].Materials Letters,2023,337:133977.
[89] SHARMA A,RAI A.Fused deposition modelling (FDM) based 3D & 4D printing:a state of art review[J].Mate-rials Today:Proceedings,2022,62:367-372.
[90] 杨新宇.4D打印碳增强导电聚乳酸复合材料驱动和传感特性研究[D].长春:吉林大学,2022.YANG X Y.Research on the actuation and sensing properties of 4D printed carbon reinforced conductive PLA compo-sites[D].Changchun:Jilin University,2022.
[91] MEHRPOUYA M,VAHABI H,JANBAZ S,et al.4D printing of shape memory polylactic acid (PLA)[J].Polymer,2021,230(9):124080.
[92] 刘少岗,李日中,王心悦,等.4D打印工艺参数对聚乳酸形状记忆特性的影响[J].工程塑料应用,2023,51(9):51-56.LIU S G,LI R Z,WANG X Y,et al.Effect of 4D printing process parameters on shape memory properties of polylactic acid[J].Engineering Plastics Application,2023,51(9):51-56.
[93] 陆婷婷.4D 打印制备 PLA 基远程驱动形状记忆复合材料及性能研究[D].上海:东华大学,2023.LU T T.Preparation of PLA-based remote drive shape memory composites by 4D printing and their properties[D].Shanghai:Donghua University,2023.
[94] 高鹏.聚乳酸/聚己内酯复合材料的仿生 4D 打印研究[D].长春:吉林大学,2023.GAO P.Bionic 4D printing of polylactic acid/polycaprolactone composites [D].Changchun:Jilin University,2023.
[95] HOSSEINZADEH M,GHOREISHI M,NAROOEI K.4D printing of shape memory polylactic acid beams:an experimental investigation into FDM additive manufacturing process parameters,mathematical modeling,and optimization[J].Journal of Manufacturing Processes,2023,85(6):774-782.
[96] SONG M Z,LI S H,ZHU G Y.Compatibilised and tou-ghened of PLA/PCL blends via modified-chitosan linking amorphous regions:4D printing and shape memory processes[J].Polymer Testing,2023,125:108105.
基本信息:
DOI:10.13250/j.cnki.wndz.24070103
中图分类号:TQ323.4
引用信息:
[1]周伟民,李小丽.聚乳酸材料的增材制造及其应用[J].微纳电子技术,2024,61(07):36-53.DOI:10.13250/j.cnki.wndz.24070103.
2024-07-15
2024-07-15