nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
WSe2薄膜的场效应和光电响应特性
基金项目(Foundation): 国家自然科学基金资助项目(62264001); 贵州省科技计划项目(QKHJC-ZK[2022]YB009,QKHJC-ZK[2024]YB521); 贵州省教育厅青年科技人才成长项目(黔教技[2024]195号); 贵州省高层次创新型人才项目(筑科合同-GCC[2023]007)
邮箱(Email):
DOI: 10.13250/j.cnki.wndz.26110301
发布时间: 2026-09-30
出版时间: 2026-09-30
网络发布时间: 2026-09-30
移动端阅读
摘要:

过渡金属二硫族化合物(TMD)因其独特的结构和物理特性备受关注。以SiO2/Si为基底,采用机械剥离方法制备多层WSe2薄膜,构造出肖特基场效应晶体管器件,研究了WSe2的场效应和光电性能。测试结果表明,WSe2肖特基晶体管呈现双极特性,空穴迁移率达40 cm2·V-1·s-1,电子迁移率为5.6 cm2·V-1·s-1;通过施加不同漏源电场,对Au-WSe2肖特基势垒进行调控,实现WSe2器件从双极特性转变为纯p型单极导电性质,辅以能带分析,揭示了该结果的内在机理。此外,在520 nm波长的光照下,测出WSe2金属-半导体-金属(MSM)光电探测器的响应度为0.8 A/W,上升时间约为40 ms。表明WSe2在电子和光电探测领域具有良好的发展前景。

Abstract:

Transition metal dichalcogenides(TMDs) have attracted much attention due to their unique structures and physical properties. With SiO2/Si as the substrate, WSe2 multilayer thin film were prepared by the mechanical exfoliation method, and Schottky field-effect transistor devices were constructed. The field effect and photoelectric properties of WSe2 were investigated. The test results show that the WSe2 Schottky transistor exhibits ambipolar characteristics, with a hole mobility of up to 40 cm2·V-1·s-1 and an electron mobility of 5.6 cm2·V-1·s-1. The Au-WSe2 Schottky barriers were modulated by applying different drain-source electric fields, enabling the WSe2 device to transform from ambipolar characteristics to pure p-type unipolar conductive properties, and the underlying mechanism was revealed coupled with band analysis. Additionally, the responsivity of the WSe2 metal-semiconductor-metal(MSM) photodetector is measured to be 0.8 A/W, and a rise time of approximately 40 ms under light irradiation with a wavelength of 520 nm. These results indicate that WSe2 has a promising future in the fields of electronics and photoelectric detection.

参考文献

[1]DARDANO P, FERRARA M A.Integrated photodetectors based on group IV and colloidal semiconductors:current state of affairs[J].Micromachines, 2020, 11(9):842.

[2]ENG P C, SONG S, PING B.State-of-the-art photodetectors for optoelectronic integration at telecommunication wavelength[J].Nanophotonics, 2015, 4(3):277-302.

[3]KATIYAR A K, THAI K Y, YUN W S, et al.Breaking the absorption limit of Si toward SWIR wavelength range via strain engineering[J].Science Advances, 2020, 6(31):eabb0576.

[4]CHOI H, CHOI S, KANG T, et al.Broad-spectrum photodetection with high sensitivity via avalanche multiplication in WSe2[J].Advanced Optical Materials, 2022, 10(22):2201196.

[5]崔月赢,宋俊明,赵伟玮,等.二维材料宽谱光电探测器研究进展[J].物理学报, 2025, 74(22):228503.CUI Y Y, SONG J M, ZHAO W W, et al.Research progress of broadband photodetectors based on two-dimensional materials[J].Acta Physica Sinica, 2025, 74(22):228503(in Chinese).

[6]MANZELI S, OVCHINNIKOV D, PASQUIER D, et al.2D transition metal dichalcogenides[J].Nature Reviews Materials, 2017, 2(8):17033.

[7]DAS S, APPENZELLER J.WSe2 field effect transistors with enhanced ambipolar characteristics[J].Applied Physics Letters, 2013, 103(10):103501.

[8]NOVOSELOV K S, JIANG D, SCHEDIN F, et al.Twodimensional atomic crystals[J].Proceedings of the National Academy of Sciences of the United States of America, 2005,102(30):10451-10453.

[9]RADISAVLJEVIC B, RADENOVIC A, BRIVIO J, et al.Single-layer Mo S2 transistors[J].Nature Nanotechnology,2011, 6(3):147-150.

[10]ZHANG S Y, CHUANG H J, LE S T, et al.Control of the Schottky barrier height in monolayer WS2 FETs using molecular doping[J].AIP Advances, 2022, 12(8):085222.

[11]MA Y F, LIU D, HAO J X, et al.High-performance flexible WSe2 flake photodetector with broadband detection capability[J].AIP Advances, 2020, 10(12):125027.

[12]DAI T J, XIAO X, FAN Z Y, et al.Barrier-free carrier injection in 2D WSe2-Mo Se2 heterostructures via Fermi-level depinning[J].Nanomaterials, 2025, 15(13):1035.

[13]AHMED S, YI J B.Two-dimensional transition metal dichalcogenides and their charge carrier mobilities in fieldeffect transistors[J].Nano-Micro Letters, 2017, 9(4):50.

[14]KATO R, UCHIYAMA H, NISHIMURA T, et al.p-type conversion of WS2 and WSe2 by position-selective oxidation doping and its application in top gate transistors[J].ACS Applied Materials&Interfaces, 2023, 15(22):26977-26984.

[15]GHOSH S, SADAF M U K, GRAVES A R, et al.Highperformance p-type bilayer WSe2 field effect transistors by nitric oxide doping[J].Nature Communications, 2025,16:5649.

[16]ZHANG H, MIAO J L, ZHANG C, et al.Improvement of p-type contact in WSe2 field-effect transistors via defect engineering[J].Nano Letters, 2025, 25(7):2803-2809.

[17]NAKAJIMA R, NISHIMURA T, UENO K, et al.Work function modulation of Bi/Au bilayer system toward p-type WSe2 FET[J].ACS Applied Electronic Materials, 2024, 6(1):144-149.

[18]夏风梁,石凯熙,赵东旭,等.二维WSe2场效应晶体管光电性能[J].发光学报, 2021, 42(2):257-263.XIA F L, SHI K X, ZHAO D X, et al.Optoelectronic performance of 2D WSe2 field effect transistor[J].Chinese Journal of Luminescence, 2021, 42(2):257-263(in Chinese).

[19]张璐,张亚东,孙小婷,等.WSe2场效应晶体管的源漏接触特性研究[J].半导体光电, 2021, 42(3):371-374,384.ZHANG L, ZHANG Y D, SUN X T, et al.Research on source/drain contact characteristics of WSe2 field effect transistors[J].Semiconductor Optoelectronics, 2021, 42(3):371-374, 384(in Chinese).

[20]KIM J, CHO K, PAK J, et al.Channel-length-modulated avalanche multiplication in ambipolar WSe2 field-effect transistors[J].ACS Nano, 2022, 16(4):5376-5383.

[21]ZHANG R, DRYSDALE D, KOUTSOS V, et al.Controlled layer thinning and p-type doping of WSe2 by vapor Xe F2[J]. Advanced Functional Materials, 2017, 27(41):1702455.

[22]PANG Y D, WU E X, XU Z H, et al.Effect of electrical contact on performance of WSe2 field effect transistors[J].Chinese Physics:B, 2021, 30(6):068501.

[23]PUDASAINI P R, STANFORD M G, OYEDELE A, et al.High performance top-gated multilayer WSe2 field effect transistors[J].Nanotechnology, 2017, 28(47):475202.

[24]陈圳,陈妍,徐中辉,等.WSe2光电性质的第一性原理研究[J].原子与分子物理学报, 2022,39(5):056007.CHEN Z, CHEN Y, XU Z H, et al.First-principles study on photoelectric properties of WSe2[J].Journal of Atomic and Molecular Physics, 2022, 39(5):056007(in Chinese).

[25]ZHANG Y X, WANG Y H, XIONG Z Z, et al.Preparation and characterization of WSe2 nano-films by magnetron sputtering and vacuum selenization[J].Nanotechnology,2018, 29(27):275201.

[26]WAGHMARE A, PRASAD M, BADE B, et al.Probing the effect of selenization on RF sputtered WSe2 thin films toward enhanced photoelectrochemical and photodetection performance[J]. Electrochimica Acta, 2024, 507:145103.

[27]XU Y H, WANG Y X, TAN C, et al.Unveiling the carrier dynamics and trapping behavior in high-performance Mo S2photodetector via screening interface impurity[J].Advanced Materials Technologies, 2026, 11(9):e02609.

[28]DAI T J, LIU Y C, FAN X D, et al.Synthesis of fewlayer 2H-Mo Se2 thin films with wafer-level homogeneity for high-performance photodetector[J]. Nanophotonics,2017, 7(12):1959-1969.

[29]WEN R C, WEI A X, TAO L L, et al.Hydrothermal synthesis of WSe2 films and their application in high-performance photodetectors[J].Applied Physics:A, 2018, 124(9):634.

[30]STRAUB F, KOHLSCHREIBER P, KECK J, et al.A simple 230 MHz photodetector based on exfoliated WSe2multilayers[J].RSC Applied Interfaces, 2024, 1(4):728-733.

基本信息:

DOI:10.13250/j.cnki.wndz.26110301

中图分类号:TN386;TB383.2

引用信息:

[1]代天军,代梅,彭朝烽,等.WSe_2薄膜的场效应和光电响应特性[J].微纳电子技术().DOI:10.13250/j.cnki.wndz.26110301.

基金信息:

国家自然科学基金资助项目(62264001); 贵州省科技计划项目(QKHJC-ZK[2022]YB009,QKHJC-ZK[2024]YB521); 贵州省教育厅青年科技人才成长项目(黔教技[2024]195号); 贵州省高层次创新型人才项目(筑科合同-GCC[2023]007)

发布时间:

2026-09-30

出版时间:

2026-09-30

网络发布时间:

2026-09-30

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文